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Popular Battery Types

 


The device (in a few words), advantages and disadvantages. Lead-acid, nickel-cadmium, nickel-metal hydride and lithium-ion batteries.

Popular Battery TypesBattery technology quietly and firmly entered our lives. Cordless phones, cell phones, cordless power tools, cameras, a variety of toys ... If all this received electricity only from ordinary acid or alkaline batteries, then a significant share of the budget of every Russian family would be spent on batteries. Therefore, you often catch yourself thinking: how did we even live without household batteries?


Batteries - These are electrochemical devices capable of storing and giving off electric energy. However, behind such a simple definition lies a wide variety of designs and principles of operation of various batteries. Evolution and technological progress have fully affected them and today in industry there are rechargeable batteriescapable of working with maximum power for literally years without recharging.

However, the average layman is only familiar with several types of batteries. Let us dwell on them in more detail.

In the on-board power systems of our cars are used starter lead acid batteries. Modern batteries This group does not require maintenance. The electrolyte in them is a solution of sulfuric acid, and the active reagents are lead oxide and lead itself. During the discharge, the reagents are reduced at the anode and cathode to lead sulfate, and an electric current passes through the electrolyte. When charging, a reverse chemical reaction occurs, and the current flows in the opposite direction.


Car batteries are called starter batteries because they are required to be willing to give a large initial current even in the most extreme conditions, for example, at an ambient temperature of -30 degrees Celsius or lower.

Starter batteries and lead-acid batteries are generally completely absent "Memory effect". This means that they absolutely do not care with what frequency and to what extent they are charged, their capacity from uneven and incomplete charging does not decrease.

In addition, lead-acid batteries are self-discharging to a minimum degree, have a relatively low cost and can withstand up to one thousand charge cycles.

But at the same time, starter batteries also have disadvantages. For example, the capacity of a lead battery, referred to a unit of its volume and mass, is small. Therefore, the lead battery can not be called compact and light. Another disadvantage of this type of battery is the fear of deep discharges. Optimum for a starter battery will be a discharge of no more than half the capacity.

In household and general industrial compact appliances, until recently, absolute leadership in prevalence was maintained nickel cadmium batteries (Ni-Cd). These are alkaline batteries, they use potassium hydroxide as an electrolyte. And the active substances in them are cadmium and nickel hydroxide (hence the name).

Ni-Cd - battery

Nickel-cadmium batteries are unique in their attitude to deep discharge. They “like” it and has a beneficial effect on the capacity and number of possible recharge cycles. In general, a nickel-cadmium battery is good in that it is able to work with constant power throughout the entire discharge cycle, producing the same current.

Like lead batteries, nickel and cadmium batteries can withstand temperature changes and are ready for a large number of recharge cycles.

The cost of nickel-cadmium batteries is slightly higher than the cost of lead batteries, but it cannot be said that the former are especially expensive.

The main disadvantage of nickel-cadmium batteries is the pronounced "memory effect". Therefore, such batteries are very harmful to constantly keep "on charge" and not fully discharge. One should not forget that cadmium is a poison, because of which there may be some difficulties when disposing of nickel-cadmium batteries.

To solve the problem of cadmium toxicity and to achieve higher operational characteristics, in the late 80s of the last century were developed rechargeable nickel metal hydride batteries (Ni-Mh). The difference between these batteries and nickel-cadmium batteries is that their cathode contains absorbed hydrogen (intermetallic). Nickel-metal hydride batteries are less susceptible to the “memory effect", have a higher specific capacity.

Ni-Mh battery

But at the same time, these batteries have a higher cost than cadmium batteries, they are able to withstand fewer charge-discharge cycles and are unable to give large currents for a long time. Because of these shortcomings, metal hydride batteries have failed to compete with cadmium batteries.

One of the most advanced and, at the same time, popular types of batteries are lithium ion batteries. On their side are both light weight, and a large resource, and the absence of a "memory effect" and self-discharge.


Lithium ion battery device quite complex: the cathode is made of graphite, and the anode is made of cobalt or manganese. During operation of the battery, lithium oxide is alternately either on the positive or on the negative electrode.

TO the disadvantages of lithium-ion batteries can be attributed, first of all, their high cost. You can add to this a small range of operating temperatures. However, these shortcomings cannot be considered significant, and the production of lithium-ion batteries is continuously gaining momentum. Moreover, more modern types of batteries, such as lithium-polymer, have not yet become widespread.

Read more about the most modern types of batteries here:

Lithium ion batteries

Gel batteries

Promising technologies:

Aluminum batteries

Carbon batteries

Graphene batteries

Alexander Molokov

See also at i.electricianexp.com:

  • Modern rechargeable batteries - advantages and disadvantages
  • Power supplies
  • How to determine the battery life of a digital camera
  • Gel batteries and their use
  • Battery memory effect

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    Comments:

    # 1 wrote: | [quote]

     
     

    In Ni-MH, the intermetallic is an anode, not a cathode. Nickel oxide cathode.

     
    Comments:

    # 2 wrote: | [quote]

     
     
    Comments:

    # 3 wrote: | [quote]

     
     

    Device for the current maintenance (desulfation) of operated batteries.

    The battery faced the problem of sulfation a few years ago, the diesel engine of my car started to get cold with cold. With a charged battery, the starter was spinning, but somehow sluggish. I looked through the materials of Battery Factor (with their unintelligible oscillogram), Valraven’s scheme (a good idea, but an illiterate technical solution), etc. I was inspired by the idea of ​​activating the process of desulfation by current pulses with steep leading edges. I assembled a simple circuit on a breadboard, set it up on a battery for the night, and started the car without problems in the morning. T.O. I reached the end of the season (I don’t go in winter), I went spring-summer without problems and in the autumn I got a new battery, extending the life of the old six-year one. He came to the conclusions: 1- the device is effective, but weak for treatment; 2- prevention of desulfation is necessary, borzh must be drunk on time. I spread the TD to repeat the device I was talking about, everyone can make it not lazy, all the components are not in short supply. Look

     
    Comments:

    # 4 wrote: tit | [quote]

     
     

    The article is not bad.Nothing, however, is said about lead VRLA AGM and gel batteries, which are also quite often used in everyday life (for example, for inverter-battery systems, or UPS for boilers ..)
    And by the way, nickel-cadmium is currently 2-3 times more expensive than lead.

     
    Comments:

    # 5 wrote: Anton | [quote]

     
     

    Memory effect of lithium ion

    Researchers at the Swiss Institute of Paul Scherrer, along with colleagues from Toyota Research in Japan, found that the widely used type of lithium-ion batteries is still subject to a negative “memory effect."

    As the study showed, frequent cycles of incomplete charging and subsequent discharge lead to the appearance of separate "microeffects of memory", which are then summed up. This is because the basis of battery operation is the release and re-capture of lithium ions, the dynamics of which become far from optimal in the case of incomplete charging.

    During the charge process, lithium ions leave particles of lithium ferrophosphate, the size of which is tens of micrometers, one after another. The cathode material begins to separate into particles with different lithium contents.

    Battery charge occurs against the background of increasing electrochemical potential. At a certain point, it reaches its limit value. This leads to an acceleration of the release of the remaining lithium ions from the cathode material, but they no longer change the total battery voltage.

    If it is not fully charged, then a certain number of particles close to the boundary state will remain at the cathode. They practically reached the barrier of lithium ion release, but did not manage to overcome it.

    During the discharge, free lithium ions tend to return to their place and recombine with ferrophosphate ions. However, on the cathode surface, they are also met by particles in the boundary state that already contain lithium. Re-capture is hindered, and the microstructure of the electrode is disturbed.

    Currently, two ways to solve the problem are being examined: making changes to the algorithms of the battery management system and developing cathodes with an increased surface area.